全文获取类型
收费全文 | 783篇 |
免费 | 17篇 |
国内免费 | 14篇 |
专业分类
安全科学 | 38篇 |
废物处理 | 21篇 |
环保管理 | 171篇 |
综合类 | 141篇 |
基础理论 | 216篇 |
环境理论 | 1篇 |
污染及防治 | 142篇 |
评价与监测 | 34篇 |
社会与环境 | 34篇 |
灾害及防治 | 16篇 |
出版年
2023年 | 15篇 |
2022年 | 9篇 |
2021年 | 29篇 |
2020年 | 19篇 |
2019年 | 36篇 |
2018年 | 31篇 |
2017年 | 34篇 |
2016年 | 35篇 |
2015年 | 22篇 |
2014年 | 24篇 |
2013年 | 66篇 |
2012年 | 41篇 |
2011年 | 47篇 |
2010年 | 40篇 |
2009年 | 36篇 |
2008年 | 46篇 |
2007年 | 35篇 |
2006年 | 37篇 |
2005年 | 29篇 |
2004年 | 24篇 |
2003年 | 20篇 |
2002年 | 26篇 |
2001年 | 17篇 |
2000年 | 9篇 |
1999年 | 9篇 |
1998年 | 3篇 |
1997年 | 4篇 |
1996年 | 6篇 |
1995年 | 6篇 |
1994年 | 5篇 |
1993年 | 5篇 |
1992年 | 2篇 |
1991年 | 5篇 |
1988年 | 1篇 |
1987年 | 5篇 |
1986年 | 2篇 |
1985年 | 4篇 |
1984年 | 2篇 |
1983年 | 5篇 |
1982年 | 6篇 |
1981年 | 5篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1969年 | 1篇 |
1955年 | 1篇 |
1954年 | 1篇 |
排序方式: 共有814条查询结果,搜索用时 15 毫秒
41.
Santamaría J Brusseau ML Araujo J Orosz-Coghlan P Blanford WJ Gerba CP 《Journal of environmental quality》2012,41(4):1246-1252
A series of miscible-displacement experiments was conducted to examine the retention and transport behavior of oocysts in natural porous media. Three soils and a model sand were used that differed in physical and geochemical properties. Transport behavior was examined under various treatment conditions to help evaluate retention mechanisms. Significant retention of oocysts was observed for all media despite the fact that conditions were unfavorable for physicochemical interactions with respect to DLVO theory. The magnitude of retention was not influenced significantly by alterations in solution chemistry (reduction in ionic strength) or soil surface properties (removal of soil organic matter and metal oxides). On the basis of the observed results, it appears that retention by secondary energy minima or geochemical microdomains was minimal for these systems. The porous media used for the experiments exhibited large magnitudes of surface roughness, and it is suggested that this surface roughness contributed significantly to oocyst retention. 相似文献
42.
Spivak-Birndorf LJ Stewart BW Capo RC Chapman EC Schroeder KT Brubaker TM 《Journal of environmental quality》2012,41(1):144-154
Sequential leaching experiments on coal utilization by-products (CUB) were coupled with chemical and strontium (Sr) isotopic analyses to better understand the influence of coal type and combustion processes on CUB properties and the release of elements during interaction with environmental waters during disposal. Class C fly ash tended to release the highest quantity of minor and trace elements-including alkaline earth elements, sodium, chromium, copper, manganese, lead, titanium, and zinc-during sequential extraction, with bottom ash yielding the lowest. Strontium isotope ratios ((87)Sr/(86)Sr) in bulk-CUB samples (total dissolution of CUB) are generally higher in class F ash than in class C ash. Bulk-CUB ratios appear to be controlled by the geologic source of the mineral matter in the feed coal, and by Sr added during desulfurization treatments. Leachates of the CUB generally have Sr isotope ratios that are different than the bulk value, demonstrating that Sr was not isotopically homogenized during combustion. Variations in the Sr isotopic composition of CUB leachates were correlated with mobility of several major and trace elements; the data suggest that arsenic and lead are held in phases that contain the more radiogenic (high-(87)Sr/(86)Sr) component. A changing Sr isotope ratio of CUB-interacting waters in a disposal environment could forecast the release of certain strongly bound elements of environmental concern. This study lays the groundwork for the application of Sr isotopes as an environmental tracer for CUB-water interaction. 相似文献
43.
We examine the wider social knowledge domain that complements technical and environmental knowledge in enabling adaptive practices through two case studies in Tanzania. We are concerned with knowledge production that is shaped by gendered exclusion from the main thrusts of planned adaptation, in the practice of irrigation in a dryland village and the adoption of fast-maturing seed varieties in a highland village. The findings draw on data from a household survey, community workshops, and key informant interviews. The largest challenge to effective adaptation is a lack of access to the social networks and institutions that allocate resources needed for adaptation. Results demonstrate the social differentiation of local knowledge, and how it is entwined with adaptive practices that emerge in relation to gendered mechanisms of access. We conclude that community-based adaptation can learn from engaging the broader social knowledge base in evaluating priorities for coping with greater climate variability. 相似文献
44.
45.
Johanna Stadmark Anne-Gret Seifert Lars Leonardson 《Atmospheric environment (Oxford, England : 1994)》2009,43(6):1182-1188
In a laboratory study we investigated 1) the potential production of nitrous oxide (N2O), methane (CH4) and carbon dioxide (CO2) and 2) the effect of nitrate (NO3?) and anaerobic N2O development on CH4 production in sediment from a recently recreated free surface water wetland (FSWW) and in soil from an adjacent meadow. We designed an experiment where production of greenhouse gases was registered at the time of maximum net development of N2O. We made additions of biodegradable carbon (glucose) and/or NO3? to sediment and soil slurries and incubated them at four temperatures (4, 13, 20, 28 °C). Gas production from both substrates was positively correlated with temperature. We also found that the sediment produced more N2O than the soil. N2O production in sediment was NO3? limited, whereas in soil carbon availability was lower and only combined additions of NO3? and glucose supported increased N2O development. CH4 production was generally low and did not differ between soil and sediment. Nor did glucose addition increase CH4 rates. The results suggest that neither soil nor sediment environment did support development of methanogenic populations. There were no clear effects of NO3? on CH4 production. However, the highest records of CH4 were found in incubations with low N2O production, which indicates that N2O might be toxic to methanogens. In summary, our study showed that transforming meadows into FSWWs implies a risk of increased N2O emissions. This does not seem to be valid for CH4. However, since N2O is almost always produced wherever NO3? is denitrified, increased N2O production in wetlands leads to reduced rates in downstream environments. Hence, we conclude that when balancing NO3? retention and global warming aspects, we find no reason to discourage future creation or restoration of wetlands. 相似文献
46.
Vanina A. Angelini Elizabeth Agostini María I. Medina Paola S. González 《Environmental science and pollution research international》2014,21(4):2531-2539
2,4-Dichlorophenol (2,4-DCP) is widely distributed in wastewaters discharged from several industries, and it is considered as a priority pollutant due to its high toxicity. In this study, the use of different peroxidase extracts for 2,4-DCP removal from aqueous solutions was investigated. Tobacco hairy roots (HRs), wild-type (WT), and double-transgenic (DT) for tomato basic peroxidases (TPX1 and TPX2) were used to obtain different peroxidase extracts: total peroxidases (TPx), soluble peroxidases (SPx), and peroxidases ionically bound to the cell wall (IBPx). All extracts derived from DT HRs exhibited higher peroxidase activity than those obtained from WT HRs. TPx and IBPx DT extracts showed the highest catalytic efficiency values. The optimal conditions for 2,4-DCP oxidation were pH 6.5, H2O2 0.5 mM, and 200 U mL?1 of enzyme, for all extracts analyzed. Although both TPx extracts were able to oxidize different 2,4-DCP concentrations, the removal efficiency was higher for TPx DT. Polyethylene glycol addition slightly improved 2,4-DCP removal efficiency, and it showed some protective effect on TPx WT after 2,4-DCP oxidation. In addition, using Lactuca sativa test, a reduction of the toxicity of post removal solutions was observed, for both TPx extracts. The results demonstrate that TPx extracts from both tobacco HRs appear to be promising candidate for future applications in removing 2,4-DCP from wastewaters. This is particularly true considering that these peroxidase sources are associated with low costs and are readily available. However, TPx DT has increased peroxidase activity, catalytic efficiency, and higher removal efficiency than TPx WT, probably due to the expression of TPX1 and TPX2 isoenzymes. 相似文献
47.
Elizabeth A. Stone Curtis J. Hedman Rebecca J. Sheesley Martin M. Shafer James J. Schauer 《Atmospheric environment (Oxford, England : 1994)》2009,43(27):4205-4213
The high-molecular weight water-soluble organic compounds present in atmospheric aerosols underwent functional-group characterization using liquid chromatography tandem mass spectrometry (LC-MS/MS), with a focus on understanding the chemical structure and origins of humic-like substances (HULIS) in the atmosphere. Aerosol samples were obtained from several locations in North America at times when primary sources contributing to organic aerosol were well-characterized: Riverside, CA, Fresno, CA, urban and peripheral Mexico City, Atlanta, GA, and Bondville, IL. Chemical analysis targeted identification and quantification of functional groups, such as aliphatic, aromatic, and bulk carboxylic acids, organosulfates, and carbohydrate-like substances that comprise species with molecular weights (MW) 200–600 amu. Measured high-MW functional groups were compared to modeled primary sources with the purpose of identifying associations between aerosol sources, high-MW aerosol species, and HULIS. Mobile source emissions were linked to high-molecular weight carboxylic acids, especially aromatic acids, biomass burning was associated with carboxylic acids and carbohydrate-like substances, and secondary organic aerosol (SOA) correlated well with the total amount of HULIS measured, whereas organosulfates showed no correlation with aerosol sources and exhibited unique spatial trends. These results suggested the importance of motor vehicles, biomass burning, and SOA as important sources of precursors to HULIS. Structural characteristics of atmospheric HULIS were compared to terrestrial humic and fulvic acids and revealed striking similarities in chemical structure, with the exception of organosulfates which were unique to atmospheric HULIS. 相似文献
48.
Elizabeth Walker Peterson Jonathan Howland 《Journal of the Air & Waste Management Association (1995)》2013,63(1):2-11
Abstract To determine covariates of radon testing behavior, we surveyed by mail a random sample of all Boston University employees (N = 915) six to nine months after they had been informed of the availability of radon testing services through the University's medical center. The response rate was 58%. Analysis suggests blue collar workers were underrepresented within the response rate. Slightly more than half of the respondents (51%) were men. The majority (69%) were under the age of 45. Twenty-seven percent of the respondents (N = 143) had tested their homes for radon. Bivariate analysis revealed important differences between radon testers and nontesters. Testers were 12 times more likely to be home owners than renters (p = 0.00), and were more knowledgeable about radon's characteristics and testing procedures (p = 0.00). Testers were more likely to view radon as a serious problem (p = 0.00), to consider radon testing efficacious (p = 0.00), and to consider themselves susceptible to exposure (p = 0.00). Testers were also less likely to perceive barriers to radon testing. We used logistic regression to compare the usefulness of the Health Belief Model and the Diffusion of Innovations Model in predicting radon testing. We concluded that the knowledge deficits and barriers to radon testing identified in this study should be targeted in radon educational interventions. 相似文献
49.
Elizabeth Mannshardt Kristen Benedict Scott Jenkins Martha Keating David Mintz Susan Stone 《Journal of the Air & Waste Management Association (1995)》2017,67(4):462-474
Air quality sensors are becoming increasingly available to the general public, providing individuals and communities with information on fine-scale, local air quality in increments as short as 1 min. Current health studies do not support linking 1-min exposures to adverse health effects; therefore, the potential health implications of such ambient exposures are unclear. The U.S. Environmental Protection Agency (EPA) establishes the National Ambient Air Quality Standards (NAAQS) and Air Quality Index (AQI) on the best science available, which typically uses longer averaging periods (e.g., 8 hr; 24 hr). Another consideration for interpreting sensor data is the variable relationship between pollutant concentrations measured by sensors, which are short-term (1 min to 1 hr), and the longer term averages used in the NAAQS and AQI. In addition, sensors often do not meet federal performance or quality assurance requirements, which introduces uncertainty in the accuracy and interpretation of these readings. This article describes a statistical analysis of data from regulatory monitors and new real-time technology from Village Green benches to inform the interpretation and communication of short-term air sensor data. We investigate the characteristics of this novel data set and the temporal relationships of short-term concentrations to 8-hr average (ozone) and 24-hr average (PM2.5) concentrations to examine how sensor readings may relate to the NAAQS and AQI categories, and ultimately to inform breakpoints for sensor messages. We consider the empirical distributions of the maximum 8-hr averages (ozone) and 24-hr averages (PM2.5) given the corresponding short-term concentrations, and provide a probabilistic assessment. The result is a robust, empirical comparison that includes events of interest for air quality exceedances and public health communication. Concentration breakpoints are developed for short-term sensor readings such that, to the extent possible, the related air quality messages that are conveyed to the public are consistent with messages related to the NAAQS and AQI.
Implications: Real-time sensors have the potential to provide important information about fine-scale current air quality and local air quality events. The statistical analysis of short-term regulatory and sensor data, coupled with policy considerations and known health effects experienced over longer averaging times, supports interpretation of such short-term data and efforts to communicate local air quality. 相似文献
50.
This study focuses on the inertial oscillation aspect of the nocturnal low-level jet (NLLJ). In the context of the Ekman model solutions, conceptual NLLJ inertial oscillation analytical frameworks proposed by Blackadar in 1957 and Shapiro and Fedorovich and van de Wiel et al. in 2010 are compared. Considering a NLLJ produced via direct numerical simulation over flat terrain with no baroclinic influence as a reference case, the deficiencies of each framework in representing a realistic NLLJ are assessed. The Blackadar theory results in unrealistic wind profiles near the surface. While extensions of Blackadar’s framework by Shapiro and Fedorovich and van de Wiel et al. produce more realistic NLLJs, the simpler approach taken by van de Wiel et al. does not describe the NLLJ wind hodograph at later times sufficiently in qualitative terms. 相似文献